刘劲刚 - 华东理工大学 - 化学与分子工程学院

研究领域

生物无机化学 (a) 无机纳米药物及靶向定点光控无机药物释放。 (b) 二氧化碳的光催化转换。 (c) 氧分子的活化还原与燃料电池电极表面催化剂。 (d) 金属蛋白酶活性中心的结构与功能模拟及小分子活化。

近期论文

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Formation of an End-On Ferric Peroxo Intermediate upon One-Electron Reduction of a Ferric Superoxo Heme, Liu J.-G., Shimizi Y., Ohta T., Naruta Y.*, J. Am. Chem. Soc. 2010, 132, 3672-3673. Spectroscopic Characterization of a Hydroperoxo-Heme Intermediate of a Synthetic Model: Conversion of a Side-on Peroxy to an End-on Hydroperoxy Complex, Liu J.-G., Ohta T., Yamaguchi Y., Ogura T., Sakamoto S., Maeda Y., Naruta Y.* Angew. Chem. Int. Ed., 2009, 48, 9262-9267(VIP paper). Highlighted in Nature, 2010, 463, 168-169, and in Angew.Chem. Int. Ed. 2010, 49, 2099-2101 Synthetic Models of the Active Site of Cytochrome c Oxidase: Influence of a Tridentate or Tetradentate Copper Chelate Bearing a His-Tyr Linkage Mimic on Dioxygen Adduct Formation by Heme/Cu Complexes, Liu J.-G., Naruta Y.*, Tani F., Chem. Eur. J. 2007, 13, 6365-6378. Characterization of the Phenoxyl Radical in Model Complexes for the CuB Site of Cytochrome c Oxidase: Steady-State and Transient Absorption Measurements, UV Resonance Raman Spectroscopy, EPR Spectroscopy, and DFT Calculations for MII-BIAIP, Nagano Y., Liu J.-G., Naruta Y.* , Ikoma T., Tero-Kubota S., Kitagawa T.*, J. Am. Chem. Soc., 2006, 128, 14560-14570. A Functional Model of the Cytochrome c Oxidase Active Site: Unique Conversion of a Heme--peroxo-CuII Intermediate into Heme-superoxo/CuI A Functional Model of the Cytochrome c Oxidase Active Site: Unique Conversion of a Heme--peroxo-CuII Intermediate into Heme-superoxo/CuI , Liu J.-G., Naruta Y.*, Tani F., Angew. Chem. Int. Ed., 2005, 44, 1836-1840. “Formation and spectroscopic characterization of the dioxygen adduct of a heme-Cu complex possessing a cross-linked tyrosine-histidine mimic: modeling the active site of cytochrome c oxidase”, Liu J.-G., Naruta Y., Tani F., Chishiro T. Tachi Y., Chem. Commun., 2004, (1), 120-121. “Interaction of [Ru(dmp)2(dppz)]2+ and [Ru(dmb)2(dppz)]2+ with DNA: Effects of the ancillary ligands on the DNA-binding behaviors”, Liu J.-G., Zhang Q.-L., Shi X.-F., Ji L.-N., Inorg. Chem., 2001, 40 (19), 5045-5050. “Shape- and enantioselective interaction of Ru(II)/Co(III) polypyridyl complexes with DNA” Ji L.-N., Zou X.-H., Liu J.-G., Coord. Chem. Rev., 2001, 216, 513-536. “Enantiomeric ruthenium(II) complexes binding to DNA: binding modes and enantioselectivity”, Liu J.-G., Ye B.-H., Zhang Q.-L., Zou X.-H., Zhen Q.-X., Tian X., Ji L.-N., J. Biol. Inorg. Chem., 2000, 5 (1), 119-128."