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研究领域

工业反应过程和反应器的工程开发研究  研究反应过程的工程特性和工程动力学;反应特性与反应器的流动、混合和传递特性在不同尺度上的匹配;反应过程优化、强化和反应器流场的调控;新型高粘聚合反应器等。 超临界流体协助的聚合物加工  以聚合物CO2发泡、聚合物改性等为对象,开展超临界流体与聚合物相互作用、超临界流体中聚合物的结构调控及相关材料的性能-结构-制备关系研究。

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D.Ch. Li, T. Liu, Ling Zhao, W.K. Yuan. Controlling Sandwich-Structure of PET Microcellular Foams Using Coupling of CO2 Diffusion and Induced Crystallization. AIChE J., 2012, 58, 2512-2523; Weizhen Sun, Meiying An, Weimin Zhong, Ling Zhao. Kinetics of COx Formation in the Homogeneous Metal/Bromide Catalyzed Aerobic Oxidation of p-Xylene. Int. J. Chem. Kine t., 2012, 277-283; J. Chen, T. Liu, L. Zhao, W.K. Yuan. Determination of CO2 solubility in isotactic polypropylene melts with different polydispersities using magnetic suspension balance combined with swelling correction. Thermochim. Acta, 2012, 530, 79– 86; J.B. Bao, T. Liu, L. Zhao, D. Barth, G.H. Hu. Supercritical carbon dioxide induced foaming of highly oriented isotactic polypropylene. Ind. Eng. Chem. Res., 2011, 50, 13387-13395; L. Li, T. Liu, L. Zhao. Direct Fabrication of Porous Isotactic Poly-1-Butene with Form I From the Melt Using CO2. Macromol. Rapid Commun., 2011, 32, 1834-1838; Lei Li, Tao Liu, Ling Zhao and Wei-kang Yuan. CO2-Induced Phase Transition of Isotactic Poly-1-butene with Form III upon Heating. Macromolecules, 2011, 44:4836–4844; Lei Li, Tao Liu, Ling Zhao, Wei-kang Yuan. CO2-induced polymorphous phase transition of isotactic poly-1-butene with form III upon annealing. Polymer, 2011, 52(15): 3488-3495; Lei Li, Tao Liu, Ling Zhao. Direct melt-crystallization of isotactic poly-1-butene with form I′ using high-pressure CO2. Polymer, 2011, 52(24): 5659-5668; J.B. Bao, T. Liu, L. Zhao, G.H. Hu. Carbon Dioxide Induced Crystallization for Toughening Polypropylene. Ind. Eng. Chem. Res.,2011, 50, 9632-9641; Weizhen Sun, Ling Zhao. Simulation of Secondary Oxidation of p-Xylene in Liquid Phase. Ind. Eng. Chem. Res. , 2011,50: 2548–2553, 2011; Da-chao Li, Tao Liu, Ling Zhao, Xiao-song Lian, and Wei-kang Yuan. Foaming of Poly(lactic acid) Based on Its onisothermal Crystallization Behavior under Compressed Carbon Dioxide,Ind. Eng. Chem. Res. 2011,50:1997–2007; D.Ch. Li, T. Liu, L. Zhao, W.K. Yuan. Foaming of linear isotactic polypropylene base on its non-isothermal crystallization behaviors under compressed CO2. J. Supercritical Fluids, 2011, 60, 89-97; L. Li, T. Liu, L. Zhao, W. K. Yuan. Effect of compressed CO2 on the melting behavior and βα-recrystallization of β-form in isotactic polypropylene. J. Supercritical Fluids, 2011, 60, 137-143; Jin-Biao Bao, Tao Liu, Ling Zhao and Guo-Hua Hu. A two-step depressurization batch process for the formation of bi-modal cell structure polystyrene foams using scCO2, J. Supercritical Fluids, 2011,55(3): 1104-1114; T. Liu, D.ch. Li, L. Zhao and W.K. Yuan .Manipulation of polymer foam structure based on CO2-induced changes in polymer fundamental properties, Particuology, 2010, 8(6): 607–612; Dachao Li, Liu Tao, Ling Zhao and Yuan W. K., Solubility and diffusivity of carbon dioxide in solid state isotactic polypropolene by the pressure-decay method. Ind. Eng. Chem. Res., 2009, 48(15), 7117-7124; Tong G. S., Liu T., Zhao L,Hu.L.X. and Yuan W. K., Supercritical carbon dioxide assisted preparation of polypropylene grafted acrylic acid with high grafted content and small gel percent. J. Supercritical Fluids, 2009,48(3), 261-268; Lei Li, Tao Liu, Ling Zhao and Wei-kang Yuan CO2-Induced Crystal Phase Transition from Form II to I in Isotactic Poly-1-butene,Macromolecules, 2009,42 (6):2286–2290; Xiu-Lei Jiang, Tao Liu, Zhi-Mei Xu, Ling Zhao, Guo-Hua Hu, Wei-Kang Yuan, Effects of crystal structure on the foaming of isotactiic polypropylene using supercritical carbon dioxide as a foaming agent. J. Supercritical Fluids, 2009,48(2), 267-17; X.L. Jiang, T. Liu, L. Zhao, Zh.M Xu, W.K. Yuan. Effect of blend morphology on foaming behaviors of polypropylene/low-density polyethylene blends. J. Cell. Plast., 2009, 45, 225-241; Weizhen Sun, Yi Pan, Ling Zhao, Xinggui Zhou. Simplified free-radical reaction kinetics for p-Xylene oxidation to terephthalic acid. Chem. Eng. Technol, 2008, 31(10): 1-9; B. Li, G. H. Hu, G. P. Cao, T. Liu, L. Zhao and W. K. Yuan. Effect of supercritical carbon dioxide-assisted nano-scale dispersion of nucleating agents on the crystallization behavior and properties of polypropylene, J. Supercritical Fluids, 2008, 44: 446-456; B.Li, X.Y. Zhu, G. H. Hu, T. Liu, G. P. Cao, L. Zhao and W. K. Yuan. Supercritical carbon dioxide-induced melting temperature depression and Crystallization of syndiotactic polypropylene, Polym. Eng. Sci, 2008, 48: 1608-1614; Li, Bin, Li Lei, Zhao Ling, Yuan, Wei Kang. In-situ FT-IR spectroscopic study on the conformational changes of isotactic polypropylene in the presence of supercritical CO2. European Polymer Journal, 2008, 44: 2619-2624; Zh. M. Xu, X. L. Jiang, T. Liu, G. H. Hu, L. Zhao and W. K. Yuan. Foaming of Polypropylene with Supercritical Carbon Dioxide. J. Supercritical Fluids, 2007, 41: 299-310; G. Sh. Tong, T. Liu, G. H. Hu, L. Zhao and W. K. Yuan. Supercritical carbon dioxide-assisted solid-state free radical grafting of methyl methacrylate onto polypropylene. J. Supercritical Fluids, 2007, 43: 64-73.

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